Heat conduction is directly analogous to diffusion of particles into a fluid, in the situation where there are no fluid currents. This type of heat diffusion differs from mass diffusion in behavior, only in as much as it can occur in solids, whereas mass diffusion is mostly limited to fluids.
Metals (e.g. copper, platinum, gold, iron, etc.) are usually the best conductors of thermal energy. This is due to the way that metals are chemically bonded: metallic bonds (as opposed to covalent or ionic bonds) have free-moving electrons which are able to transfer thermal energy rapidly through the metal.
As density decreases so does conduction. Therefore, fluids (and especially gases) are less conductive. This is due to the large distance between atoms in a gas: fewer collisions between atoms means less conduction. Conductivity of gases increases with temperature. Conductivity increases with increasing pressure from vacuum up to a critical point that the density of the gas is such that molecules of the gas may be expected to collide with each other before they transfer heat from one surface to another. After this point in density, conductivity increases only slightly with increasing pressure and density.
Convection is the transfer of thermal energy by the movement of molecules from one part of the material to another. As the fluid motion increases, so does the convective heat transfer. The presence of bulk motion of the fluid enhances the heat transfer between the solid surface and the fluid.
Radiation is the transfer of heat energy through empty space. All objects with a temperature above absolute zero radiate energy at a rate equal to their emissivity multiplied by the rate at which energy would radiate from them if they were a black body. No medium is necessary for radiation to occur, for it is transferred through electromagnetic waves; radiation works even in and through a perfect vacuum. The energy from the Sun travels through the vacuum of space before warming the earth.
By Jiamin.